Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
Author(s): Thomas Netscher | Patrick BohrerJournal: Molecules ISSN 1420-3049
Volume: 7; Issue: 8; Start page: 601; Date: 2002;
Original page
Keywords: Alkylation reagents | SN2 substitution reactions | steric hindrance | sulfonic esters | sulfur-oxygen bond cleavage.
ABSTRACT
The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
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