Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two FunctionsAuthor(s): Mauricio Gomes Constantino | Altamiro Xavier de Souza | Gil Valdo JosÃƒÂ© da Silva
Journal: Molecules ISSN 1420-3049
Volume: 7; Issue: 6; Start page: 475; Date: 2002;
Keywords: Diels-Alder adducts | Intramolecular interactions | 1 | 4-Diols oxidation | Cyclic phosphite
In this paper we describe the synthesis of a ÃŽÂ³,ÃŽÂ´-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.