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Novel Easy Preparations of Some Aromatic Iodine(I, III, and V) Reagents, Widely Applied in Modern Organic Synthesis

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Author(s): Lech Skulski

Journal: Molecules
ISSN 1420-3049

Volume: 8;
Issue: 1;
Start page: 45;
Date: 2003;
Original page

Keywords: Aromatic iodides | aromatic hypervalent iodine reagents | oxidative anion metatheses in ionic halides

ABSTRACT
We report our novel (or considerably improved) methods for the synthesis of aromatic iodides, (dichloroiodo)arenes, (diacetoxyiodo)arenes, [bis(trifluoroacetoxy)-iodo]arenes, iodylarenes and diaryliodonium salts, as well as some facile, oxidative anion metatheses in crude diaryliodonium or tetraalkylammonium halides and, for comparison, potassium halides. All our formerly published papers were discussed and explained in our review “Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, Poland” (1990-2000) [1]. Our newest results are discussed below.
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