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Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

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Author(s): S. Servi | C. Topaloglu

Journal: Molecules
ISSN 1420-3049

Volume: 9;
Issue: 1;
Start page: 22;
Date: 2004;
Original page

Keywords: Nozaki-Hiyama reaction | Organochromium reagents | Hetero- aromatic aldehydes

ABSTRACT
Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.
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